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Kinetics of the N-chlorination of 2-aminobutyric, 3-aminobutyric, 3-aminoisobutyric and 4-aminobutyric acids in aqueous solution

✍ Scribed by J. M. Antelo; F. Arce; J. C. Pérez-moure

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 390 KB
Volume: 24
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550241207

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✦ Synopsis

Abstract

We studied the kinetics of the N‐chlorination of 2‐aminobutyric, 3‐aminoisobutyric, and 4‐aminobutyric acids by sodium hypoclorite in strongly alkaline aqueous solution. As in the case of other amines, the rate of formation of the four N‐chloroamino acids was proportional to the concentrations of hypochlorite and amino acid, and inversely proportional to the concentration of hydroxyl ions. A reaction mechanism compatible with these results is proposed and discussed. © John Wiley & Sons, Inc.

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