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Decomposition kinetics of the N-bromoaminoacids, N-bromoalanine, N-bromo-2-aminobutyric acid, and N-bromonorvaline

✍ Scribed by Juan M. Antelo; Florencio Arce; Juan Crugeiras; José L. Armesto

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
441 KB
Volume
25
Category
Article
ISSN
0538-8066

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✦ Synopsis

A kinetic study of the decomposition reactions of N-bromoalanine, N-bromo-2-aminobutyric acid, and N-bromonorvaline shows them to be first-order with respect to N-bromoaminoacid concentration and independent of both excess aminoacid and pH over the interval pH 9-11. In this pH range the mean rate constants at 298 K were 1.20 X s-l and 1.28 X s-', respectively.

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