✦ LIBER ✦

Kinetics of the Mu + H2 and Mu + D2 reactions from 610 to 850 K

✍ Scribed by David M. Garner; Donald G. Fleming; Randall J. Mikula

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 714 KB
Volume: 121
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)87160-8

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✦ Synopsis

The bimolecular rare conslanls for the thermal chemical reaclions 01 muonium (Mu): Mu + H2 + MuH + H and Mu+ D2 + MuD+D. have been measured in the temperalure range 610-650 K. For the hydrogen reaction. log A (err? molecule-' s-l)= -9.6&0.4md fC,-13.8+1.5 kcol mole-'. while for the druvxium rexCon log A (cm3 molecule-' s-') = -9.12 1.2 and Ea = 17.22 4.1 kcal mole-'. These results compare well with variational wmsition slate theory calcularions carried OUL on the Liu-Siegbnhn-Truhlar-Horowitz potemial surface.

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