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Kinetics of the homolytic interaction of methallyl chloride with CCl4and steric effects in theβ-elimination of the chlorine atom

✍ Scribed by B. A. Englin; R. D. Ismailov; R. Kh. Freidlina

Book ID
112421503
Publisher
Springer
Year
1972
Tongue
English
Weight
438 KB
Volume
21
Category
Article
ISSN
1573-9171

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The competitive reactions of Br atoms with CH, and CD, were studied over the temperature range of 562' to 637°K. Over this temperature interval, the kinetic isotope effect, k,/k,, varied from 3.05 to 2.47 for the reactions Br + CH, -% HBr + CH, The rate constant ratio k,/k, , expressed in Arrhenius