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The Kinetic Isotope Effects in the Reactions of Four Ethene Isotopologues with Chlorine and Bromine Atoms

โœ Scribed by Enghoff, Martin B.; von Hessberg, Philipp; Nielsen, Claus J.; Johnson, Matthew S.


Book ID
127126606
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
65 KB
Volume
107
Category
Article
ISSN
1089-5639

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Kinetic isotope effects in the reactions
โœ Toshitsugu Yokota; Richard B. Timmons ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 462 KB ๐Ÿ‘ 1 views

The competitive reactions of Br atoms with CH, and CD, were studied over the temperature range of 562' to 637ยฐK. Over this temperature interval, the kinetic isotope effect, k,/k,, varied from 3.05 to 2.47 for the reactions Br + CH, -% HBr + CH, The rate constant ratio k,/k, , expressed in Arrhenius