Isotope Effects in the Reactions of Chloroform Isotopologues with Cl, OH, and OD
β Scribed by Nilsson, Elna J. K.; Johnson, Matthew S.; Nielsen, Claus J.
- Book ID
- 120335871
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 397 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
Guided-ion beam methods were used to measure the absolute cross sections for OH+/OD + derived from O + and H20/D20 collisions over the range of 0.25-20 eV relative energy. The cross sections for the isotopic homologues have the same form, a bimodal behavior that appears to be related to the thermoch
The kinetics of the reactions OH Ο© Br 2 : HOBr Ο© Br (1) and OD Ο© Br 2 : DOBr Ο© Br (3) have been studied in the temperature range 230-360 K and at total pressure of 1 Torr of helium using the discharge-flow mass spectrometric method. The following Arrhenius expressions were obtained either from the k