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Kinetics of the homogeneous hydrogenation of cyclohexene catalyzed by hydridocobalt complexes formed in situ from CoH(N2)(PPh3)3

✍ Scribed by Éva Balogh-hergovich; Gábor Speier; László Markó


Book ID
108352002
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
561 KB
Volume
66
Category
Article
ISSN
0022-328X

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Homogeneous hydrogenation of imines cata
✍ V. Herrera; B. Muñoz; V. Landaeta; N. Canudas 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 168 KB

The regioselective hydrogenation of some imines to the corresponding amines is efficiently catalyzed by [Ir(COD)(PPh 3 ) 2 ]PF 6 (1) and [Rh(COD)(PPh 3 ) 2 ]PF 6 (2) at 60 • C and 200 psi of H 2 . The kinetics of the hydrogenation of N-(␤-naphthyl methylene) aniline (N␤NA) with [Ir(COD)(PPh 3 ) 2 ]P