Homogeneous hydrogenation of imines cata
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V. Herrera; B. Muñoz; V. Landaeta; N. Canudas
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Article
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2001
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Elsevier Science
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English
⚖ 168 KB
The regioselective hydrogenation of some imines to the corresponding amines is efficiently catalyzed by [Ir(COD)(PPh 3 ) 2 ]PF 6 (1) and [Rh(COD)(PPh 3 ) 2 ]PF 6 (2) at 60 • C and 200 psi of H 2 . The kinetics of the hydrogenation of N-(-naphthyl methylene) aniline (NNA) with [Ir(COD)(PPh 3 ) 2 ]P