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Amine Products and Catalyst Poisoning in the Homogeneous H 2 Hydrogenation of Imines Catalyzed by the [Rh(COD)(PPh 3 ) 2 ]PF 6 Precursor

✍ Scribed by Marcazzan, Paolo; Patrick, Brian O.; James, Brian R.


Book ID
127106755
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
61 KB
Volume
22
Category
Article
ISSN
0276-7333

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πŸ“œ SIMILAR VOLUMES


Homogeneous hydrogenation of imines cata
✍ V. Herrera; B. MuΓ±oz; V. Landaeta; N. Canudas πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 168 KB

The regioselective hydrogenation of some imines to the corresponding amines is efficiently catalyzed by [Ir(COD)(PPh 3 ) 2 ]PF 6 (1) and [Rh(COD)(PPh 3 ) 2 ]PF 6 (2) at 60 β€’ C and 200 psi of H 2 . The kinetics of the hydrogenation of N-(␀-naphthyl methylene) aniline (N␀NA) with [Ir(COD)(PPh 3 ) 2 ]P