✦ LIBER ✦

Kinetics of the gas-phase thermal elimination of N-alkyl-pyrazoles

✍ Scribed by Jorge Daniel Perez; Leonardo Miguel Phagouape

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 307 KB
Volume: 19
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550190608

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✦ Synopsis

The kinetic study of the gas-phase thermal elimination reactions of N-ethyl-3,5 dimethyl-pyrazole ( I ) , N-ethyl-pyrazole ( I I 1, N-sec-butyl-pyrazole ( I I I 1, and N-tert-butyl-pyrazole (IV) using a flow system is reported. After obtaining activation parameters for I we carried out competitive reactions with II, III and IV using I as internal standard to obtain their E,. The values of A(AH,") calculated for II, ZII and ZV agree with the little differences in E , experimentally found.

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