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Kinetics of the gas-phase thermal elimination of (β-chloro ethyl)-pyrazole

✍ Scribed by Jorge Daniel Perez; Leonardo Miguel Phagouape

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
246 KB
Volume
20
Category
Article
ISSN
0538-8066

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✦ Synopsis

Flash vacuum pyrolysis of (p-chloro ethyl)-pyrazole was studied. Pyrazole elimination and vinyl chloride formation were found. Competitive reactions with (p-chloro ethyl)-pyrazole were carried out using N-ethyl-3,5-dimethyl pyrazole as internal standard to obtain the kinetic parameters (Ea). A(bHf") for this reaction was calculated.

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