The relative rate technique has been used to determine the rate constants for the reaction of chlorine atoms with a series of oxygenated organic species. Experiments were performed a t 295 t 2 K and atmospheric pressure of synthetic air or nitrogen. The decay rates of the organic species were measur
Kinetics of the gas phase reaction of chlorine atoms with a series of alkenes, alkynes and aromatic species at 295 K
β Scribed by Timothy J. Wallington; Loretta M. Skewes; Walter O. Siegl
- Book ID
- 108043230
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 628 KB
- Volume
- 45
- Category
- Article
- ISSN
- 1010-6030
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π SIMILAR VOLUMES
Using relative rate techniques the reactions of chlorine and fluorine atoms with HC(O)F have been determined to proceed with rate constants of and respectively. Stated errors reflect statistical uncertainty; possible systematic uncertainties could add additional 10% and 20% ranges to the values of k
Using a relative rate technique the reactions of chlorine and fluorine atoms with CF3CHO have been determined to proceed with rate constants of (1.8 % 0.4) x and (2.7 2 0.1) x lo-" cm3 molecule-' s-', respectively. Experiments were performed a t 295 ? 2 K and 700 torr total pressure of nitrogen. The