Kinetics of the Gas-Phase Addition of the Ethyl Radical and the tert -Butyl Radical to NO
✍ Scribed by Dilger, Herbert; Stolmár, Martina; Himmer, Ulrich; Roduner, Emil; Reid, Ivan D.
- Book ID
- 127184302
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 65 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
The kinetics of the reactions CsH,+OH( t M) +products ( + M ) ( I ) were studied at room temperature by pulse radiolysis of C2H6/H20/SFb mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k, is (7.1 f 1.0) x lOto M
## Abstract Azoethane was irradiated in the presence of carbon monoxide in the temperature range of 238 to 378 K. Kinetic parameters for the addition of ethyl radicals to carbon monoxide and for the decomposition of propionyl radicals were determined. The rate constants were found to be log __k__(c