Kinetic Study of Gas-Phase Reactions of OH and NO 3 Radicals and O 3 with iso-Butyl and tert -Butyl Vinyl Ethers
β Scribed by Zhou, Shouming; Barnes, Ian; Zhu, Tong; Benter, Thorsten
- Book ID
- 127373170
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 394 KB
- Volume
- 116
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The temperature dependence of the rate coefficients for the OH radical reactions with iso-propyl acetate (k 1 ), iso-butyl acetate (k 2 ), sec-butyl acetate (k 3 ), and tert-butyl acetate (k 4 ) have been determined over the temperature range 253-372 K. The Arrhenius expressions obtained are: were
Using relative rate methods, rate constants have been measured for the gas-phase reactions of 3-methylfuran with NO, radicals and 0, at 296 ? 2 K and atmospheric pressure of air. The rate constants determined were (1.31 ? 0.46) X lo-'' cm' molecule-' s-' for the NO, radical reaction and (2.05 ? 0.52