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Kinetics of the formation, decomposition, and disproportionation reactions of N-chlorobutylamines

✍ Scribed by Juan M. Antelo; Florencio Arce; Marí C. Castro; Juan Crugeiras; Juan C. Pérez-Moure; Pilar Rodríguez

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
682 KB
Volume
27
Category
Article
ISSN
0538-8066

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✦ Synopsis

The formation of N-chlorobutylamines is a reaction of order one with respect to hypochlorite and amine, and order -1 with respect to OH-. Kinetic studies show that N-chlorobutylamines undergo decomposition in basic aqueous media, and disproportionation (with formation of N,N-dichloramines) in acidic media, mechanisms are put forward for both these processes.

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