✦ LIBER ✦

Disproportionation kinetics of N Cl-n-propylamine and N Cl-isopropylamine

✍ Scribed by Juan M. Antelo; Florencio Arce; Mercedes Parajo; Pilar Rodriguez; Angel Varela

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 309 KB
Volume: 24
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550241109

No coin nor oath required. For personal study only.

✦ Synopsis

The kinetics of the disproportionation of N -C1-n-propylamine and N-C1-isopropylamine to the corresponding N, N-dichloramines were found to be a second order with respect to the N-chloramine. The influence of amine concentration, pH, buffers, ionic strength, and temperature were also studied. The observed influence of pH supports a reaction mechanism which allowed estimation of the protonation constants of the chloramines studied. The influence of buffers, which was studied for both the above chloramines and N -C1-3-aminopropanol, reflects general acid catalysis, for which a mechanism is proposed. Bronsted's equation was fitted to the catalytic constants obtained therefrom so as to estimate the values of the parameter a for these three N-chloramines.

📜 SIMILAR VOLUMES

Disproportionation Kinetics of N-Chlorom

Disproportionation Kinetics of N-Chloromethylamine and N-Chloroethylamine

✍ J. M. Antelo; F. Arce; M. Parajó; P. Rodríguez 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 223 KB

C−Cl and Si−Cl Activation by P,N-Chelate

C−Cl and Si−Cl Activation by P,N-Chelated PtII Complexes

✍ Frank Stöhr; Dietmar Sturmayr; Guido Kickelbick; Ulrich Schubert 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB

VLE data for CO2-CF2Cl2, N2-CO2, N2-CF2C

VLE data for CO2-CF2Cl2, N2-CO2, N2-CF2Cl2 and N2-CO2-CF2Cl

✍ W. Dorau; I.M. Al-Wakeel; H. Knapp 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 712 KB

## Knowledge about vapour-liquid equilibria (VL E) is required as a basis of reliable calculations for separation processes. Correlations available for the prediction of T, p, x, y data are less accurate for mixtures at high pressures and mixtures containing supercritical components. The results of

Determinations of the rate constants of

Determinations of the rate constants of the reactions Cl + N3Cl and N3 + NO at 295 K

✍ John Brunning; Michael A.A. Clyne 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 439 KB

Synthesis and Crystal Structure of [(n-B

Synthesis and Crystal Structure of [(n-Bu)4N][W6Cl18].

✍ Simone Dill; Markus Stroebele; H.-Juergen Meyer 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 56 KB 👁 1 views

Kinetics of the formation, decomposition

Kinetics of the formation, decomposition, and disproportionation reactions of N-chlorobutylamines

✍ Juan M. Antelo; Florencio Arce; Marí C. Castro; Juan Crugeiras; Juan C. Pérez-Mo 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 682 KB

The formation of N-chlorobutylamines is a reaction of order one with respect to hypochlorite and amine, and order -1 with respect to OH-. Kinetic studies show that N-chlorobutylamines undergo decomposition in basic aqueous media, and disproportionation (with formation of N,N-dichloramines) in acidic