𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics of the addition of mono- and binitroxide radicals to olefins

✍ Scribed by L.V. Ruban; A.L. Buchachenko; M.B. Neiman


Book ID
118358173
Publisher
Elsevier Science
Year
1967
Weight
460 KB
Volume
9
Category
Article
ISSN
0032-3950

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Addition of methoxy radicals to olefins
✍ E. A. Lissi; G. Massiff; A. Villa πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 321 KB

## Abstract The addition of methoxy radicals to several olefins has been studied by a competitive method at 127Β°C in gas phase. The thermal decomposition of dimethyl peroxide was used as methoxy radical source. The rate of addition to the double bond was measured relative to the oxidation of carbon

Polar Effects in the Addition of Alkyl R
✍ Priv.-Doz. Dr. Bernd Giese; Dipl.-Chem. JΓΌrgen Meister πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 198 KB πŸ‘ 2 views

**The presence of a negative partial charge on the benzylic carbon atom in the transition state** __(1)__ can be deduced from the experimentally determinable Hammett Ο± values. Alkyl radicals R^Λ™^ are accordingly seen to develop nucleophilic properties during addition to olefins. equation image