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Kinetics of superoxide dismutase- and iron-catalyzed nitration of phenolics by peroxynitrite

✍ Scribed by Joseph S. Beckman; Harry Ischiropoulos; Ling Zhu; Mark van der Woerd; Craig Smith; Jun Chen; Joseph Harrison; James C. Martin; Michael Tsai

Book ID
115709197
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
822 KB
Volume
298
Category
Article
ISSN
0003-9861

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πŸ“œ SIMILAR VOLUMES

Nitration and hydroxylation of substitut
Nitration and hydroxylation of substituted phenols by peroxynitrite. Kinetic feature and an alternative mechanistic view
✍ Nobuaki Nonoyama; Kazuhiko Chiba; Kaori Hisatome; Hitomi Suzuki; Futoshi Shintan πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 257 KB

The reaction of peroxynitrite (ONOO-) with a series ofpara-substituted phenols has been examined in aqueous phosphate buffer and acetonitrile solutions. Major products were the corresponding 2-nitro derivative and the 4-substituted catechol. Kinetic study showed good correlation with Hammett (rp Γ· p