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Carbon Dioxide Modulation of Hydroxylation and Nitration of Phenol by Peroxynitrite

✍ Scribed by Jean-Noël Lemercier; Sarojini Padmaja; Rafael Cueto; Giuseppe L. Squadrito; Rao M. Uppu; William A. Pryor

Book ID
115566640
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
257 KB
Volume
345
Category
Article
ISSN
0003-9861

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Nitration and hydroxylation of substitut
Nitration and hydroxylation of substituted phenols by peroxynitrite. Kinetic feature and an alternative mechanistic view
✍ Nobuaki Nonoyama; Kazuhiko Chiba; Kaori Hisatome; Hitomi Suzuki; Futoshi Shintan 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 257 KB

The reaction of peroxynitrite (ONOO-) with a series ofpara-substituted phenols has been examined in aqueous phosphate buffer and acetonitrile solutions. Major products were the corresponding 2-nitro derivative and the 4-substituted catechol. Kinetic study showed good correlation with Hammett (rp ÷ p