The concept of using precise kinetic measurements to aid in the characterization of organic compounds has been applied to sugars. Hydroxylamine reacts with sugars to form oximes; the rate of the reaction can be conveniently followed spectrophotometrically. At pH 6.5 and with an excess of hydroxylami
โฆ LIBER โฆ
Kinetics of Oxime Formation; Temperature Coefficients of Rate of Formation of Several Oximes
โ Scribed by Fitzpatrick, Francis W.; Gettler, Joseph D.
- Book ID
- 127141303
- Publisher
- American Chemical Society
- Year
- 1956
- Tongue
- English
- Weight
- 890 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0002-7863
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The following lines of evidence establish that oxime formation from pyruvic acid occurs with ratedetermining carbinolamine dehydration under acidic and neutral conditions. First, saturation effects observed at pH 7 are strongly suggestive of carbinolamine accumulation, requiring that dehydration of
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