The kinetics of the permanganate-hypophosphite redox reaction has been studied over a wide range of pH by using a stopped-flow technique. It has been found that the reaction leads to the formation of phosphite and orthophosphate, and that the molar ratio of the final products depends on pH. The prop
Kinetics of oxidation of hypophosphite ion by platinum(IV) in an alkaline medium
β Scribed by K. K. Sen Gupta; Surajit Maiti; Pratik K. Sen
- Publisher
- Springer
- Year
- 1981
- Tongue
- English
- Weight
- 325 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0340-4285
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The kinetics of oxidation of tetrahydrofurfuryl alcohol by dihydroxydiperiodatonickelate (IV) complex in the temperature range of 20-35Β°C has been studied by spectrophotometry in aqueous alkaline medium. The reaction order in [Ni(IV)] was found to be unity and that in [alcohol] to be 1.64-1.69. The
## The kinetics of the osmium( VIII) catalyzed oxidation of Te(IV) by octacyanomolybdate( V) and octacyanotungstate(V) tins have been investigated in an alkaline medium. The reactions are first order with respect to M(CN)i-ion (M = MO, W) and catalyst concentrations. The second order reaction rate