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Kinetics of oxidation of copper(I) by molecular oxygen in perchloric acid-acetonitrile solutions

✍ Scribed by Gray, Robert D.


Book ID
126000337
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
831 KB
Volume
91
Category
Article
ISSN
0002-7863

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Oxidation of Cu(I) by oxygen in concentr
✍ N. Papassiopi; A. Gaunand; H. Renon πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 497 KB

The homogeneous oxidation of cuprous chloride in 2 M NaCl solutions by dissolved molecular oxygen was studied, using a batch reactor, at constant pH and temperature. The rate of homogeneous reaction is represented by the expression: R = k[O,] [CU(I)]'.~ with k = 2.8 x 106cm4-5mol-' 's-l where square