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Kinetics and mechanism of oxidation of hypophosphorous acid with silver(I) in aqueous perchloric acid solutions

โœ Scribed by Indrayan, A. K.; Mishra, S. K.; Gupta, Y. K.

Book ID
126478442
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
463 KB
Volume
20
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of electron trans
Kinetics and mechanism of electron transfer reactions in aqueous solutions: Silver(I) catalyzed oxidation of aspartic acid by cerium (IV) in acid perchlorate medium
โœ Indu Sharma; Vijai Devra; Divya Gupta; C. M. Gangwal; P. D. Sharma ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 501 KB

Silver(1) catalyzed oxidation of aspartic acid by cerium(1V) was studied in acid perchlorate medium. The stoichiometry of the reaction is represented by the eq. (i) Dimeric cerium(IV) species has been indicated and employed in calculations of monomeric cerium(IV) species concentrations. The reactio