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Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbene

โœ Scribed by Michael T.H. Liu; Robert G. Chapman; Roland Bonneau

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
284 KB
Volume
63
Category
Article
ISSN
1010-6030

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โœฆ Synopsis

Photolysis of 3-chloro-3-benzyldiaiirine in tetramethylethylene gives E-and Z-fi-chlorostyrenes and cyclopropans. Relative rate studies show that the styrenes to cyclopropane ratio increases with increasing diazirine concentration_ This permits the determination of the ratio k,/ki= 8 where kD is the rate constant for the reaction of carbene with diazirine and ki is the rate constant for the 1,Zhydrogen atom shift of carbene. Laser Aash uhotolvsis

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