Intermolecular and Intramolecular Transamidation Reactions
โ Scribed by M. Eugenia Gonzalez-Rosende; Encarna Castillo; Jamal Lasri; Jose Sepulveda-Arques
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Photolysis of 3-chloro-3-benzyldiaiirine in tetramethylethylene gives E-and Z-fi-chlorostyrenes and cyclopropans. Relative rate studies show that the styrenes to cyclopropane ratio increases with increasing diazirine concentration\_ This permits the determination of the ratio k,/ki= 8 where kD is th
## Abstract PausonโKhand reactions of functionalized allenes with different alkynes give cyclopentenones with generally high regioโ and stereoselectivities. The allenes react through their external double bonds, giving cyclopentenones with exocyclic double bond at their ฮฒ positions and predominantl