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Intramolecular and Intermolecular Schmidt Reactions of Alkyl Azides with Aldehydes.

โœ Scribed by Huey-Lih Lee; Jeffrey Aube


Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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The title diazenes are found to be new and convenient reagents for the regioselective electrophilic amination of various electron-rich arenes. The products serve as potent precursors of arylsubstituted hydrazines, ureas, and 1,2,4-triazolinediones. In the absence of activated arenes the diazenes un