The oxidation of ethylenediamine by diperiodatoargentate (III) ion has been studied by stopped-flow spectrophotometry. Kinetics of this reaction involves two steps. The first step is the complexation of silver (III) with the substrate and is over in about 10 ms. This is followed by a redox reaction
Kinetics of Hydrolysis of Diperiodatoargentate(III) Ion and its Reduction by Paracetamol
β Scribed by Mohammad Ilyas; Zaheer Khan
- Book ID
- 106547086
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 270 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
Diperiodatoargentate(III) oxidizes nitrilotriacetic acid in a mildly basic medium to produce formaldehyde and ammonia. This reaction follows a complex kinetic behaviour. The axial binding of NTA to silver(III) complex takes place on the millisecond time-scale with a second-order rate constant of (4.
The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-