Kinetics of base hydrolysis ofO-bonded pentaammineglycinatocobalt(III) and pentaammine-β-alaninatocobalt(III) ions
✍ Scribed by Pratap C. Tripathy; Prakash Mohanty; Rabindra K. Nanda
- Book ID
- 105045497
- Publisher
- Springer
- Year
- 1985
- Tongue
- English
- Weight
- 205 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0340-4285
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## Abstract The kinetics of base hydrolysis of (αβ S)‐(o‐methoxy benzoato) (tetraethylenepentamine)cobalt(III) obeyed the rate law: __k__~obs~ = __k__~OH~[OH^−^], in the range 0.05 ⩽ [OH^−^]~__T__~, mol dm^−3^ ⩽ 1.0, I = 1.0 mol dm^−3^, and 20.0–40.0°C. At 25°C, __k__~OH~ = 13.4 ± 0.4 dm^3^ mol^−1^
The kinetics of base hydrolysis of (CUPS) (salicylato) (tetraethylenepentamine) cobalt(II1) have been investigated in aquo-organic solvent media at 15.0 f t, "C < 40.0, and I = 0.10 mol dm (C104-) using propane-2-01 (570% v/v), t-butanol(560% v/v), acetone (570% v/v, acetonitrile (550% v/v), and eth