Kinetics and mechanism of oxidation of some reducing sugars by diperiodatoargentate(III) in alkaline medium
β Scribed by K. Venkata Krishna; P. Jaya Prakash Rao
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 316 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0340-4285
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Diperiodatoargentate(III) oxidizes nitrilotriacetic acid in a mildly basic medium to produce formaldehyde and ammonia. This reaction follows a complex kinetic behaviour. The axial binding of NTA to silver(III) complex takes place on the millisecond time-scale with a second-order rate constant of (4.
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