Kinetics of Hydrogen Peroxide Accumulation in Electrosynthesis from Oxygen in Gas-Diffusion Electrode in Acidic and Alkaline Solutions
β Scribed by G. A. Kolyagin; V. L. Kornienko
- Book ID
- 111560537
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2003
- Tongue
- English
- Weight
- 90 KB
- Volume
- 76
- Category
- Article
- ISSN
- 1070-4272
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AM&act-The intermediate peroxide scheme for the oxygen electrode has been tested by experiments on oxygen reduction and hydrogen peroxide decomposition at silver electrodes in potassium hydroxide solutions (0.1, 1.0 and 5.0 M) at 25Β°C. The scheme is found appropriate in interpreting the obaervations
The photolysis of strong alkaline solutions of H 2 O 2 yields , which in the presence of molecular oxygen forms the ozonide radical ion, . A detailed kinetic study on the reaction mechanisms involved during formation and decay of radical ions in these solutions, in the presence and absence of added