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Kinetics of geminate recombination of aromatic free radicals

✍ Scribed by I.V. Khudyakov; Yu.I. Kiryukhin; A.I. Yasmenko

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 392 KB
Volume: 74
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)85253-5

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✦ Synopsis

Wmosecond laser flash photol~s~s tcchmques ~erc used to observe the gemmate recombmntlon hmetlcs of 2-(j'dlphe-II) lamlnophcnyI)-lndandlone-I ,3-l I radicals (R) m vasehne od at O=C The bmetics are closely described by the Kofman-Burshtem model The rate of dlifuslon-controlled recombmatron of R by random encounters m the bulk 1%~ also measured. The hmrrlcs of gcmmare rccombmatlon and recombmatlon m the bulk are described b) the same parameters (drffusxon coefiiclent (1 8 = 0 6) x IO-* cm?/s and reactlon radms 13 1 4).

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