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Time resolved observation of geminate recombination in metal-free phthalocyanine

✍ Scribed by Zoran D. Popovic


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
256 KB
Volume
100
Category
Article
ISSN
0009-2614

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✦ Synopsis


Delayedcollection-field measurements of carrier _eeneration and delayed fluorescence in metal-free phthalocyanine have been shown to exhibit the same time dependence. This indicates the esistence of geminate electron-hole pairs with survival times estending to tens of milliseconds.


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The.magnetic circular dichroism and absorption spectra of (Y metal-free pfithalocyanine have been measured at 300 and 8 K. Using both techniques the visible spectrum can be ar;dysed'as,two transitions to degenerate and two to nondegenerhte excited states. These excited states are assigned as the dif