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Observation of Davydov splitting in the MCD spectra of α metal-free phthalocyanine

✍ Scribed by B.R. Hollebone; M.J. Stillman

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
357 KB
Volume
29
Category
Article
ISSN
0009-2614

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✦ Synopsis

The.magnetic circular dichroism and absorption spectra of (Y metal-free pfithalocyanine have been measured at 300 and 8 K. Using both techniques the visible spectrum can be ar;dysed'as,two transitions to degenerate and two to nondegenerhte excited states. These excited states are assigned as the differently split pairs of Davydov components derived from the lowest energy E, and AZ" states of the mor.omeric 18n electron phtholocyanine ring.

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