Bergamot ¯avedo (Citrus bergamia Risso) was extracted by supercritical carbon dioxide (SC-CO 2 ) at three dierent conditions: 80 bar of pressure at 408C of temperature, 90 bar at 508C, 100 bar at 608C. The density value was similar for every experiment and was limited between 282 and 288 g/dm 3 . Th
Kinetics of extraction of coal-tar pitch components with supercritical carbon dioxide
✍ Scribed by S. Marković; Z. Marković; R. I. McCrindle; B. R. Simonović
- Book ID
- 111491022
- Publisher
- Versita
- Year
- 2007
- Tongue
- English
- Weight
- 170 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0366-6352
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✦ Synopsis
Abstract
The extraction of a coal-tar pitch with supercritical carbon dioxide was performed under optimal pressure, flow rate, and three different constant temperatures. The extraction kinetics was examined for each temperature and it was surprisingly found that the extraction rate of most components was governed by the first-order kinetics. It was assumed that this deviation from typical models of supercritical fluid extraction kinetics was caused by high pitch concentrations and low solubilities of the components.
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Predictions are given for the solubilities of four compounds (naphthalene, phenanthrene, phenol, and 2-naphthol) in carbon dioxide at six temperatures between 40 "C and 100 "C and pressures up to 240 bar. The data are intended to be relevant to the extraction of coal-gasification tars. The Peng-Robi