Kinetics of ethylene polymerization in the presence of a homogeneous catalyst based on a bis(phenoxyimine) complex of zirconium(IV)
✍ Scribed by A. A. Barabanov; N. V. Semikolenova; M. A. Mats’ko; L. G. Echevskaya; V. A. Zakharov
- Book ID
- 110171308
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 155 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0023-1584
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The effects of polymerization time and temperature on the molecular weight and molecular weight distribution of polyethylene, produced over homogeneous catalyst bis[N-(3-tert-butyl salicylidene)anilinato]zirconium(IV) dichloride t Bu-L 2 ZrCl 2 /MAO have been studied. The data on the number of activ
## Abstract Suitably activated, (Cp\*){N(^__t__^Bu)C(Me)N(Et)}ZrMe~2~ is known to initiate the ‘living’ and isotactic‐selective polymerization of alk‐1‐enes, and it can be used to synthesize block copolymers and stereoblock polymers. We report a full molecular kinetic investigation of propene, but‐