Kinetics of ethylene homopolymerization reactions and ethylene/1-hexene copolymerization reactions using a supported Ziegler-Natta catalyst was carried out over a broad range of reaction conditions. The kinetic data were analyzed using a concept of multicenter catalysis with different centers that r
✦ LIBER ✦
Kinetics of ethylene polymerization at high temperature with Ziegler–Natta catalysts
✍ Scribed by Y. V. Kissin; D. L. Beach
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 612 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0021-8995
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Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit several features which differentiate them from polymerization reactions of ␣-olefins: a relatively low ethylene reactivity, higher polymerization rates in the presence of ␣-olefins, a high reaction order with respect to ethy