Kinetics of chemical polarization of31P nuclei in decomposition reactions of certain peroxides
✍ Scribed by D. G. Pobedimskii; Yu. Yu. Samitov; É. I. Gol'dfarb; P. A. Kirpichnikov
- Book ID
- 112364948
- Publisher
- Springer
- Year
- 1974
- Tongue
- English
- Weight
- 292 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-5760
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Chemical polarisation of ^31^P nuclei was discovered and quantitatively measured in the peroxide‐phosphite system. The qualitative interpretation of the net polarisation of ^31^P nuclei and of its sign in the products of the radical reactions in the presence of phosphites is given withi
Proton chemical polarization was observed in methyl butyrate, y-butyrolactone and in some other products of the dimethyl perdiglutarate decomposition reaction. The polarization pattern of the a-CH, and P-CH, groups in butyrolactone is just as one would expect in the products of the CH,OCH,CH,CH, rad