✦ LIBER ✦

Chemical polarization of nuclei. Proton polarization during thermal decomposition reaction of dimethyl perdiglutarate

✍ Scribed by A. V. Ignatenko; A. V. Kessenikh

Publisher: John Wiley and Sons
Year: 1971
Tongue: English
Weight: 128 KB
Volume: 3
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270030619

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✦ Synopsis

Proton chemical polarization was observed in methyl butyrate, y-butyrolactone and in some other products of the dimethyl perdiglutarate decomposition reaction. The polarization pattern of the a-CH, and P-CH, groups in butyrolactone is just as one would expect in the products of the CH,OCH,CH,CH, radical which has left the pair of identical radicals. Thus butyrolactone is formed from the CH30CH,CH,CH, radical by means of intramolecular cyclization and elimination of the methyl radical.

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