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Chemical polarization of nuclei. PMR spectra of decomposition products of dimethyl peroxydiphthalate

✍ Scribed by A. V. Kessenikh; S. V. Rykov; E. K. Starostin; G. I. Nikishin

Publisher: John Wiley and Sons
Year: 1971
Tongue: English
Weight: 129 KB
Volume: 3
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270030316

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✦ Synopsis

Abstract

Chemical polarization of protons was observed in methyl benzoate formed during the thermal decomposition of dimethyl ester of peroxydiphthalic acid. The polarization pattern of methyl benzoate aromatic protons was very different in this case from that observed during the thermal decomposition of acetyl benzoyl peroxide. The unpolarized products formed from the methoxy radical, CH~2~O and CH~3~OH, were found in the mixture of decomposition products of this peroxide and were identified by means of PMR spectroscopy.

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