The anodic dark and photodissolution of n-Gap and n-GaAs has been investigated in aqueous H,SO,, NaCIO, and KOH solutmns. Evaluation with the aid of a recently developed dynamical theory of photoelectrochemical processes points to kinetic control of the anodic dark dissolution and of the photocurren
Kinetics of anodic dark and photodissolution of n-GaAs and n-GaP electrodes
β Scribed by W. Lorenz; B. Wolf
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 441 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
This paper provides a theoretical survey and further experimental data of kiietically controlled stationary dark and photocurrents on n-GaAs and n-Gap electrodes. The mechanism of anodic photodissolution is treated in greater detail, taking explicitly into account a sequence of kinetic steps. The possibility to detect partial charge transfer steps in stationary photocurrentvoltage curves is examined and related experimental data are discussed. Effects of photoinduced surface layer formation which takes place under certain conditions are briefly reported.
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