Kinetics of acid-catalysed dissociation of N,N′-dialkyl-1,10-phenanthroline-2,9-dimethanamine copper(II) complexes
✍ Scribed by Hongwei Sun; Huakuan Lin; Zhifen Zhou; Guanghua Zhao; Shourong Zhu; Xuncheng Su; Yunti Chen
- Book ID
- 110246551
- Publisher
- Springer
- Year
- 2000
- Tongue
- English
- Weight
- 111 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0340-4285
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📜 SIMILAR VOLUMES
The crystal structure of the title compound, [CuCl 2 -(C 14 H 12 N 2 )(H 2 O)], previously reported by Preston & Kennard [J. Chem. Soc. A (1969). pp. 2955±2958], has been redetermined. The recognition of an inversion twin allowed a much better re®nement.
In the title compound, [CuCl 2 (C 14 H 12 N 2 )(H 2 O)], there are two molecules in the asymmetric unit; both Cu atoms are fivecoordinate with a distorted trigonal-bipyramidal geometry. Molecules are linked into a three-dimensional network by O-HÁ Á ÁCl and C-HÁ Á ÁCl hydrogen bonds. The packing is
Benzoato-j 2 O,O 0 0 0 )chlorido(2,9-dimethyl-1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)