Kinetics and Product Study of the Reaction of CH 3 Radicals with O( 3 P) Atoms Using Time Resolved Time-of-Flight Spectrometry
β Scribed by Fockenberg, Christopher; Hall, Gregory E.; Preses, Jack M.; Sears, Trevor J.; Muckerman, James T.
- Book ID
- 126986773
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 181 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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The reactions of 0( 'P) atoms with CH,OH and CH,CHOH have been measured directly for the first time. In a discharge flow reactor CH,OH/CH,CHOH profiles were monitored at ambient temperature and in an excess of 0 atoms by a mass spectrometer, working at low electron energies. The effect of subsequent
## Abstract The reaction of atomic chlorine with CH~3~CH~2~OD has been examined using a discharge fast flow system coupled to a mass spectrometer combined with the relative rate method (RR/DF/MS). At 298 Β± 2 K, the rate constant for the Cl + CH~3~CH~2~OD reaction was determined using cyclohexane as