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Atmospheric Chemistry of Pivalaldehyde and Isobutyraldehyde: Kinetics and Mechanisms of Reactions with Cl Atoms, Fate of (CH 3 ) 3 CC(O) and (CH 3 ) 2 CHC(O) Radicals, and Self-Reaction Kinetics of (CH 3 ) 3 CC(O)O 2 and (CH 3 ) 2 CHC(O)O 2 Radicals

✍ Scribed by Le Crâne, Jean-Paul; Villenave, Eric; Hurley, Michael D.; Wallington, Timothy J.; Nishida, Satoshi; Takahashi, Kenshi; Matsumi, Yutaka

Book ID
126525606
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
231 KB
Volume
108
Category
Article
ISSN
1089-5639

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UV absorption spectra of HO2, CH3O2, C2H5O2, and CH3C(O)CH2O2 radicals and mechanism of the reactions of F and Cl atoms with CH3C(O)CH3
✍ Ole J. Nielsen; Matthew S. Johnson; Timothy J. Wallington; Lene K. Christensen; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB

## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0