Kinetics and mechanistic study of manganese(II)-catalyzed cerium(IV) oxidation of thiamine hydrochloride in aqueous perchloric acid medium by stopped flow technique
โ Scribed by Naik, D. V.; Byadagi, K. S.; Nandibewoor, S. T.; Chimatadar, S. A.
- Book ID
- 120711913
- Publisher
- Springer Vienna
- Year
- 2013
- Tongue
- English
- Weight
- 540 KB
- Volume
- 144
- Category
- Article
- ISSN
- 0026-9247
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๐ SIMILAR VOLUMES
## Abstract The kinetics of oxidation of vanillin (VAN) by diperiodatocuprate(III) (DPC) in alkaline medium at a constant ionic strength of 0.50 mol dm^โ3^ was studied spectrophotometrically. The reaction between DPC and vanillin in alkaline medium exhibits 1:2 stoichiometry (vanillin: DPC). The re
Silver(1) catalyzed oxidation of aspartic acid by cerium(1V) was studied in acid perchlorate medium. The stoichiometry of the reaction is represented by the eq. (i) Dimeric cerium(IV) species has been indicated and employed in calculations of monomeric cerium(IV) species concentrations. The reactio