Oxidation of clindamycin phosphate by cerium(IV) in perchloric acid medium – A kinetic and mechanistic approach
✍ Scribed by Badi, Seema S.; Tuwar, Suresh M.
- Book ID
- 122201401
- Publisher
- Elsevier
- Year
- 2017
- Tongue
- English
- Weight
- 813 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1878-5352
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## Abstract The oxidation of D‐mannitol by cerium(IV) has been studied spectrophotometrically in aqueous sulfuric acid medium at 25°C at constant ionic strength of 1.60 mol dm^−3^. A microamount of ruthenium(III) (10^−6^ mol dm^−3^) is sufficient to enhance the slow reaction between D‐mannitol and
The kinetics of the oxidation of dimethylsulfoxide by Cerium(IV) in perchloric acid has been investigated spectrophotometrically. The water role has been elucidates by using acidity criteria. A tentative mechanism consistent with the kinetics is dis- ## Kinetische Untersuchung der Oxidation von Dim