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Kinetics and Mechanisms of Hydrolysis and Aminolysis of Thioxocephalosporins

✍ Scribed by Tsang, Wing Y.; Dhanda, Anupna; Schofield, Christopher J.; Page, Michael I.

Book ID
120519875
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
109 KB
Volume
69
Category
Article
ISSN
0022-3263

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Nucleophilic substitution reactions of cycloalkylmethyl arenesulfonates (C m H 2n Οͺ 1 CH 2 OSO 2 C 6 H 4 Z) with anilines (XC 6 H 4 NH 2 ) in methanol at 65.0 Β°C were studied. The reactivity order (n =4>6>7>5) reflects largely the order of steric effect of the ring size (SEs term) except for n = 5,