𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and Mechanism of the Reactions of Anilines with Ethyl S -Aryl Thiocarbonates

✍ Scribed by Castro, Enrique A.; Leandro, Leonardo; Millán, Pablo; Santos, José G.


Book ID
121267361
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
72 KB
Volume
64
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Kinetics and mechanism of the aminolysis
✍ Hyuk Keun Oh; Yun Ho Lee; Ikchoon Lee 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 51 KB 👁 2 views

The kinetics and mechanism of the reactions of O-ethyl S-(Z)aryl thiocarbonates with (X)benzylamines in acetonitrile at 45.0ЊC are studied. Relatively small values of ␤ X (␤ nuc ) ϭ 0.6 ϳ 0.8 and ␤ Z (␤ lg ) ϭ Ϫ0.5 ϳ Ϫ0.7 together with a negative cross-interaction constant XZ (ϭ Ϫ0.47) and failure o