The kinetics and mechanism of the reactions of O-ethyl S-(Z)aryl thiocarbonates with (X)benzylamines in acetonitrile at 45.0ЊC are studied. Relatively small values of  X ( nuc ) ϭ 0.6 ϳ 0.8 and  Z ( lg ) ϭ Ϫ0.5 ϳ Ϫ0.7 together with a negative cross-interaction constant XZ (ϭ Ϫ0.47) and failure o
✦ LIBER ✦
Kinetics and Mechanism of the Aminolysis of O -Aryl S -Methyl Thiocarbonates
✍ Scribed by Castro, Enrique A.; Aliaga, Margarita; Santos, José G.
- Book ID
- 127157457
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 136 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0022-3263
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