Kinetics and mechanism of the reaction of iodine with tetrahydrofuran. Carbon-hydrogen bond dissociation energy in tetrahydrofuran
β Scribed by Cruickshank, Frank R.; Benson, Sidney W.
- Book ID
- 125453427
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 397 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The gas phase reaction I, + HCOOCH, +HI + CH,I + CO, has been studied spectrophotometrically in a static system over the pressure ranges I, (6-39 torr) and HCOOMe (28-360 torr). In the temperature range 293-356', the initial rate of disappearance of I, is first order in [HCOOMe] and half-order in [I
The title reaction has been investigated in the temperature range of 494-545 K. During the early stages of reaction the only observed products were silyl iodide and hydrogen iodide. Initial rates were found to obey the rate law over a wide range of initial iodine and monosilane pressures. Secondary
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