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Kinetics and Mechanism of the Gas Phase Reaction between Iodine and Formaldehyde and the Carbon-Hydrogen Bond Strength in Formaldehyde 1a

✍ Scribed by Walsh, R.; Benson, S. W.

Book ID
127037972
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
723 KB
Volume
88
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Carbon–hydrogen bond strengths in methyl
Carbon–hydrogen bond strengths in methyl formate and the kinetics of the reaction with iodine
✍ Richard K. Solly; Sidney W. Benson πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 507 KB

The gas phase reaction I, + HCOOCH, +HI + CH,I + CO, has been studied spectrophotometrically in a static system over the pressure ranges I, (6-39 torr) and HCOOMe (28-360 torr). In the temperature range 293-356', the initial rate of disappearance of I, is first order in [HCOOMe] and half-order in [I

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The title reaction has been investigated in the temperature range of 494-545 K. During the early stages of reaction the only observed products were silyl iodide and hydrogen iodide. Initial rates were found to obey the rate law over a wide range of initial iodine and monosilane pressures. Secondary