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Kinetics and Mechanism of the Reaction between Thiosulfate and Chlorine Dioxide

✍ Scribed by Horváth, Attila K.; Nagypál, István

Book ID
126999470
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
84 KB
Volume
102
Category
Article
ISSN
1089-5639

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Kinetics and mechanism of the reaction b
Kinetics and mechanism of the reaction between thiosulfate and chlorite ions at 90°C
✍ István Nagypál; Irving R. Epstein; Kenneth Kustin 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 396 KB

The kinetics of the oxidation of S20:-by CIOz-have been studied in aqueous alkaline solution at 90°C using classical titrimetric methods to follow the course of the reaction. The reaction takes place according to the stoichiometry SzO: - + 2C10z-+ 20H-= 2S042-+ 2Cl-+ H 2 0 even in large SzO:excess.